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Mass balance and equation of state. You have a 1 m 3 container filled with N 2 that is at an initial pressure P =

Mass balance and equation of state.
You have a 1m3 container filled with N2 that is at an initial pressure P=5 bars and temperature of T=300K. You can consider the N2 to be an ideal gas ) for the entirety of this problem. A leak develops in the container and you will learn in transport that the leak rate often depends linearly on the pressure difference between the inside and outside, or mathematically Q=K(P-P0),
where Q is the flow rate (moles/sec),P0 is the pressure outside the tank, and K is the leak rate coefficient. In our case we will take a leak rate of K=0.01molessec bar . The outside pressure is always atmospheric, P0=1.01 bar (you can approximate P0 to be 1 bar).
a) Calculate the initial flow rate out of the tank (moles ?sec).
b) If the leak continues at this flow rate at all times (i.e. it does not slow down with the decreasing pressure), calculate the time it takes for the pressure in the tank to reach P=3 bars. Hint: Do a molar balance, and calculate the number of moles you start with at P=5 bars, and how much is left in tank at P=3 bars.
c) Part b is a decent estimate, but not the best estimate as the flow rate will slow down as the pressure is decreased. Using a molar balance approach with the instantaneous molar leak rate, calculate the amount of time it takes to reach P=3 bars. You will need to set up your equations correctly, and perform an integration.
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