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Microelectronic devices are made by depositing many layers of thin films onto silicon wafers. For example, thin films of arsenic for silicon are deposited by

Microelectronic devices are made by depositing many layers of thin films onto silicon wafers. For example, thin films of arsenic for silicon are deposited by chemical vapour deposition (CVD) of arsine (AsH3) vapour onto the surface of a silicon wafer. The chemical reaction for this CVD process is,
AsH3(g)-> As(s)+3/2 H2(g)
The process operates at a pressure of 300 Pa and a temperature of 600 oC. In many CVD reactors, the gas phase over the thin film is not mixed. Furthermore, at 600 oC the surface reaction is very fast. Consequently, the molecular diffusion of AsH3 vapour to the surface of the wafer can be assumed to control the rate of As(s) formation.
A mixture of arsine and hydrogen gas continuously flows into the reactor at a molar ratio of 4:1 H2:AsH3. A diffuser 6 cm above the wafer provides a quiescent gas space over the growing As(s) film.
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