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Minerals a and b are described by this reaction: Mg(OH) 2 (solid) MgO (solid) + H 2 O (gas). What is the stable product when
Minerals "a" and "b" are described by this reaction: Mg(OH)2 (solid) <=> MgO (solid) + H2O (gas). What is the stable product when pressure equals 700 MPa and the temperature is 600 degrees celsius?
Gibbs free E at any T and p can be found with this equation: GT', p' = G0 - T'T ref (SdT + Vsolid (P' - Pref) + ff ref (RT/ f)df .
The fugacity coefficient of H2O at 600 degrees celsius and 700 MPa equals 0.67. Whereas the solids in the reaction cannot be compressed.
fH0 (kJ/ mol) | S0 (J/mol K) | fG0 (kJ/ mol) | Vol (cc/mol) | ||
mineral a | Mg(OH)2 | -972.8 | 77.25 | -853.5 | 25.89 |
mineral b | MgO | -599.4 | 35.84 | -695.44 | 09.17 |
Water (gas) | -277.99 | 165.5 | -221.4 | 30507 |
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