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Moody [ 1 ] studied the efficiency of a GC separation of 2 - butanone on a dinonyl phthalate column. Evaluating plate height as a

Moody [1] studied the efficiency of a GC separation of 2-butanone on a dinonyl phthalate
column. Evaluating plate height as a function of flow rate gave a van Deemter equation for
which A is 1.65 mm, B is 25.8 mmmL/min, and C is 0.0236 mmmin/mL.
a) Using Microsoft Excel, plot a graph of H versus u for flow rates in the range of 5120
mL/min. Your graph must include curves due to the contributions of all the terms (i.e. Curve for A, B and C and the overall curve)
b) For what range of flow rates does each term in the Van Deemter equation have the
greatest effect?
c) How much is the optimum flow rate for this column?
d) How much is the height of a theoretical plate for the flow rate in part C ?

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