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One hundred moles of a saturated mixture of n-hexane (nC6H14) in N2 at 1atm and at 20C (i.e. at its dew point) is placed in
One hundred moles of a saturated mixture of n-hexane (nC6H14) in N2 at 1atm and at 20C (i.e. at its dew point) is placed in a piston and cylinder system. The Antoine equation for n-hexane vapor pressure, p is: log10(p)=6.88555[1175.817/(T+224.867)],wherep=vaporpressure(mmHg)andT(=)C Assuming negligible solubility of N2 in n-hexane: a. Estimate the vapor phase mole fraction of nC6H14 in the mixture at 20C and 1 atm. b. The inlet valve to the cylinder is closed for the mixture from part (a) and the system is heated to 35C keeping total pressure at 1 atm by expanding the volume of the cylinder. This mixture is then pressurized isothermally at 35C to the dew point pressure at 35C. What is the pressure at which the first droplet of hexane "dew" forms part (a)? 10% extra credit: What total pressure at 35C is needed to condense 40% of the original nC6 from the mixture in part (a)? This extra credit part does not need to be solved in the 20 -minute limit for (a) \& (b) , since it requires more \& thinking
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