One should determine the calcium concentration in blood serum samples using ion-selective calcium electrode. The calibration curve for the ion-selective electrode is presented in the table below. Average the potential from four measurements for the blood serum sample was measured at 20.3mV. [Ca 2+] mV 0.0001 -27.7 0.001 2.7 0.01 31.9 0.1 65.1 a) Calculate the concentration of calcium in the blood serum sample. b) Calculate the absolute and relative standard deviation for -log10 [Ca2 +] (pCa). Note that comes from four measurements. c) Explain why a concentrated buffer or an inert electrolyte is added to all solutions when performing these measurements. d) Explain why one does not add a concentrated buffer or an inert electrolyte to all solutions for pH measurements with glass membrane electrodes.