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pC - pH diagram EX) Find the pH,pOH,[CN],[HCN], and [Na+]in a 1mM sodium cyanide (NaCN) solution at 25C; neglect ionic effects. (1) Species: [Na+],[H+],[HCN],[CN], and

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pC - pH diagram EX) Find the pH,pOH,[CN],[HCN], and [Na+]in a 1mM sodium cyanide (NaCN) solution at 25C; neglect ionic effects. (1) Species: [Na+],[H+],[HCN],[CN], and [OH] (2) EQ1:H2OH++OH;Kw=1014=[H+][OH] (3) EQ2:CN+H2OHCN+OH;Kb=104.7=[OH][HCN]/[CN] (4) MB1:CT,Na=[Na+]=103M (5) MB2: CT,CN=[HCN]+[CN]=103M (6) PC: [HCN]+[H+]=[OH]

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