PLEASE ATTEMPT ONLY IF YOU CAN ANSWER ALL THE PARTS OTHERWIES I WILL GIVE 3 DOWNVOTE

1-1 For the ammonia-synthesis reaction, N2 + 3H2 2NH3, if the ra 42 / 693 N, is (-9), what is the rate with respect to (a) Hz and (b) NH3 in 1-2 The rate law for the reaction C2H4Br2 + 3KI CH4 + 2KBr + Klz in an mien suvem, wiucn can be written as A + 3B - products, has been found to be (-ra) = KACACB, with the rate constant ka = 1.34 L mol-'h-1 at 74.9C (Dillon, 1932). (a) For the rate of disappearance of KL. (-18), what is the value of the rate constant kg ? (b) At what rate is KI being used up when the concentrations are CA = 0.022 and CB= 0.22 mol L-!? (c) Do these values depend on the nature of the reactor in which the reaction is carried out? (They were obtained by means of a constant-volume batch reactor.) 1-3 (a) In Example 1-4, of the 5 rate quantities (one for each species), how many are independent (i.e., would need to be determined by experiment)? (b) Choose a set of these to exclude "hy, and relate Thy to them. 14 For each of the following systems, determine C (number of components). a permissible set of components, R (maximum number of independent chemical equations), and a proper set of chemical equations to represent the stoichiometry. In each case, the system is represented by a list of species followed by a list of elements. (a) {(NH4CIO4, Cl2, N2O, NOCI, HCI, H2O, N2, O2, CIO2), (N, H, CI, O)) relating to explosion of NHACIO4 (cf. Segraves and Wickersham, 1991, equation (10). (b) {(C(gr), CO(g), CO2(g), Zn(g), Zn(0), ZnO(s)), (C, 0, Zn)) relating to the production of zinc metal (Denbigh, 1981, pp 191-193). (Zn(g) and Zn(O) are two different species of the same substance Zn.) (c) {(Cl2, NO, NO2, HCI,N20, H2O, HNO3,NH4C104, HC10462H20), (CI, N, O, H) }relating to the production of perchloric acid (Jensen, 1987). a