Plot a graph, similar to the one below, with the new variables (1)/(T) on the x -axis and LnP on the y -axis. Use the
Plot a graph, similar to the one below, with the new variables
(1)/(T)
on the
x
-axis and
LnP
on the
y
-axis. Use the Microsoft Excel program to help you. If the original pressure versus temperature data for the unknown liquid conforms to the behavior predicted by the Claussius-Clapeyron Model, this plot should yield a straight line.\
(4.0*1)/(.9936)(-5472.1)k
\ The slope will yield a numerical value for:\
-(\\\\Delta Hv)/(R)
\ (K)\ The y-intercept will yield a numerical value for:
(\\\\Delta Hv)/(RT_(b))+LnP_(0),
(no units)\ The slope and y-intercept values can be extracted from the graphed data by using the "Trendline" function in the "Microsoft Excel" program. Using the known values for R and
P_(0)
, determine the values for
\\\\Delta H_(V)
and
T_(b)
\ \\\\table[[Parameter,Value],[
\\\\Delta H_(v)
,KiloJoules / mole],[
T_(b)
,],[Correlation Factor,]]\
-5472.1K
\
er=21.899
\
P=33\ y=-5472,1x+21.899\ R^(2)=.9936
\ 33
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