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Points ) The production of ethylene glycol from ethylene chlorohydrin and sodium bicarbonate reacts as follows: C O 2 ( g ) u a r

Points) The production of ethylene glycol from
ethylene chlorohydrin and sodium bicarbonate reacts as
follows:
CO2(g)uarrCH2OHCH2Cl+NaHCO2(CH2OH)2+NaCl+
The reaction (elementary) is carried out isothermally at 30
C in a semi-batch reactor. The reactor can hold a maximum
of 2500dm3. Assume constant density. A 1.5M solution of
ethylene chlorohydrin is fed at a rate of 0.1moles? minute to
1500dm3 of a 0.75M solution of sodium bicarbonate. The
specific reaction rate at 30C is 5.1dm3mole** hour. Higher
temperatures create undesirable side reactions. (tf+th+td)
=4.5 hours.
(a). Analyze the conversion, reaction rate, concentrations of
reactants and products, and number of moles of glycol
produced.
(b) Suppose you can vary the flow rate of ethylene
chlorohydrin from 0.01 to 200 moles per minute. Maximize
the production of glycol in 24 hours.
(c) Suppose the ethylene chlorohydrin is fed at a rate of
0.15molesmi
ute until the reactor is full. Analyze the
conversion as a function of time.
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