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Polymer Physics 5 . 2 2 . Consider a spherical micelle made of f deblock copolymers. The insoluble block consists of N B monomers of

"Polymer Physics" 5.22. Consider a spherical micelle made of f deblock copolymers. The
insoluble block consists of NB monomers of size bB and its Flory interaction parameter with
solvent is B.
(i) Calculate the size Rcore of the core of the micelle.
(ii) Calculate the interfacial energy of the core (per chain).
(iii) Calculate the size of the micelle Rmicelle in an athermal solvent for the outer block
A=0. Calculate the free energy of the corona (per chain).
(iv) Optimize the aggregation number f by balancing the interfacial and corona parts of
free energy per chain.
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