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predictions. ExperimentalmeasurementsofVaughanandCollins [ Ind . Eng. Chem., 3 4 , 8 8 5 ( 1 9 4 2 ) ] forthepropane isopentanesystem , at 1
predictions.
ExperimentalmeasurementsofVaughanandCollinsIndEng.
Chem.,forthepropaneisopentanesystematF
andpsia,showapropaneliquidphasemolefractionofin
equilibriumwithavaporphasemolefractionofCalculate:
aTheKvaluesforCandiCfromtheexperimentaldata.
bTheKvaluesofCandiCfromRaoultslawassumingvapor
pressuresatFofandpsia,respectively.
Comparetheresultsof aandbAssumingtheexperimental
valuesarecorrect,howcouldbetterestimatesof theKvaluesbe achieved?Torespondtothisquestion,comparetherigorousKi
giLfiLfiV totheRaoultslawexpressionKiPs
iP
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