Answered step by step
Verified Expert Solution
Link Copied!

Question

1 Approved Answer

Problem 3. This problem pertains to poly(ethylene oxide) (PEO) chains having a molecular weight of 15,000g/mol. For PEO, use an estimate for a PEO Kuhn

image text in transcribed

Problem 3. This problem pertains to poly(ethylene oxide) (PEO) chains having a molecular weight of 15,000g/mol. For PEO, use an estimate for a PEO Kuhn length of 1.5nm and a molecular weight of the statistical Kuhn of about 90g/mol. A) Calculate the root mean square end-end distance of a PEO chain. B) Calculate the spring constant and the force needed to stretch a single PEO coil to an end-end extension of 25nm. Recalculate the force for an extension of 40nm. Recall that kT (which appears in the formula for the spring constant, is equal to 4.111021J at room temperature.) C) Calculate the spring constant for a PEO chain having a molecular weight of 100,000g/mol. D) Now consider the stretching force to maintain a chain having 15,000g/mol at an extension of 40nm. If there were many chains weighing a total of a gram, all of which are stretched to the same extent, you might imagine the material would deform. (When al the chains stretch the same way, it is called affine deformation.) How much stretching force would be needed to hold a gram of chains at an end-end distance of 40nm ? Wording the same question another way: if you know the force stretch a single chain to an end-end distance of 40nm, what would be the force to stretch a gram of chains by the same amount? What percent strain (change in length divided by original length) is this

Step by Step Solution

There are 3 Steps involved in it

Step: 1

blur-text-image

Get Instant Access to Expert-Tailored Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

blur-text-image

Step: 3

blur-text-image

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Chemical Engineering An Introduction

Authors: Morton Denn

1st Edition

1107011892, 9781107011892

More Books

Students also viewed these Chemical Engineering questions