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Problem 5(15%). Use Excel to generate the phase diagram of pure water (P in log scale from 0.1Pa to 10MPa; T in linear scale from
Problem 5(15%). Use Excel to generate the phase diagram of pure water (P in log scale from 0.1Pa to 10MPa; T in linear scale from 173K to 548K ) according to the information given in the textbook: (i) the first brief illustration on p. 102 (ice-water phase boundary); (ii) the second brief illustration on p. 102 (water-vapor phase boundary); (iii) the brief illustration on p. 49(Hsub=51.1kJmol1 at 0C); (iv) the triple point of water =273.16K and 611Pa on p. 105; (v) the critical point of water = 647K and 218atm=2.25107Pa (Table 3.1). (1atm=1.01325bar,1bar=105Pa) Hint: dTdp=(273.15K)(1.634106m3mol1)6.008103Jmol1=1.346107PaK1dTdlnp=(8.314JK1mol1)(373.2K24.07104Jmol1=3.51102K1 Problem 5(15%). Use Excel to generate the phase diagram of pure water (P in log scale from 0.1Pa to 10MPa; T in linear scale from 173K to 548K ) according to the information given in the textbook: (i) the first brief illustration on p. 102 (ice-water phase boundary); (ii) the second brief illustration on p. 102 (water-vapor phase boundary); (iii) the brief illustration on p. 49(Hsub=51.1kJmol1 at 0C); (iv) the triple point of water =273.16K and 611Pa on p. 105; (v) the critical point of water = 647K and 218atm=2.25107Pa (Table 3.1). (1atm=1.01325bar,1bar=105Pa) Hint: dTdp=(273.15K)(1.634106m3mol1)6.008103Jmol1=1.346107PaK1dTdlnp=(8.314JK1mol1)(373.2K24.07104Jmol1=3.51102K1
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