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PROBLEMLER A r nler eklinde bir reaksiyonda e er reaksiyon h z kar mdaki An n n . ci kuvveti ile do ru orant l

PROBLEMLER
A rnler eklinde bir reaksiyonda eer reaksiyon hz karmdaki Ann
n.ci kuvveti ile
doru orantl ise reaksiyon
n.ci mertebedendir denir. rA, birim zamanda ve birim hacimde
reaksiyona giren mol says ise o zaman
rA(mollitre.s)=kCAn dir.
Burada litre), reaktant Ann konsatrasyonu; k ise orant sabiti olup buna reaksiyon hz
sabiti denir. Hz yukardaki ifade ile verilen reaksiyona
n.ci metebeden reaksiyon denir. Hz
sabiti k scakln ok kuvvetli bir fonksiyonu olmakla beraber konsantrasyondan bamszdr.
a) Birince mertebeden (n=1) bir reaksiyonun izotermal kesikli bir reaktrde olutuunu
varsayalm. A'ya gre bir komponent denklii yazarak
CA=CA0.exp(-kt) ifadesini tretiniz.
b) Slfrl klorr SO2Cl2SO2+Cl2 reaksiyonuna gre gaz faz bozunmasna uramaktadr.
Reaksiyon izotrmal, sabit hacimde oluuyor.SO2Cl2 'nin zamana kar konsantrasyonlar
aadaki tabloda verildii gibi llmtr.
Buna gre verilerin birinci mertebeden bir reaksiyona uyduunu grafiksel olarak gsteriniz.
k nn deeri ve birimi nedir?
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