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Q 3 . The liquid phase isothermal reaction, A + B = P + Q follows a 2 n d order kinetics, - r A

Q3. The liquid phase isothermal reaction,
A+B=P+Q
follows a 2nd order kinetics,
-rA=kCACB
The reaction is carried out in two CSTRs in series. The reactors operate at a
temperature of 50C and a pressure of 2atm. The rate constant at the operating
condition is 36.36m3*kmol-1*hr- The feed flowrate is 1.8m3*h-1 and the
concentrations of A and B are the same and equal to 0.07kmol.m-3. The desired
conversion is 75%.
(a) Determine the conversion in the 1st reactor when the total volume of the reactor
cascade is minimum.
[22 marks]
(b) Use the conversion determined in section (a) or assume a conversion of 54% in
1st reactor and determine the volume of the individual reactors and their
sequence.The liquid phase isothermal reaction, A+B=C+D follows a 2 nd order reaction (1st order in A and 1st order in B). The feed volumetric flowrate is 3.0\times 10^(-4)m^(3)s^(-1). The feed is equimolar and the initial concentration of A is 0.12kmolm^(-3). The rate constant is 1.0\times 10^(-2)m^(3)kmol^(-1)s^(-1). The reactor conversion is 70%. Apply the graphical method, (a) to determine the volume of a CSTR.(a) to determine the total volume of a cascade of three identical CSTRs in series.
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