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Question 3 : Ammonium Nitrate ( N H 4 N O 3 ) is a form of fertiliser which can also be used as an

Question 3:
Ammonium Nitrate (NH4NO3) is a form of fertiliser which can also be used as an explosive. It is
derived from the Haber Bosch reaction [1], which produces Ammonia (NH3), which is then oxidized
to form nitric acid. The formed Nitric Acid (HNO3) is reacted with Ammonia to form Ammonium
Nitrate. The three reactions that occur in the production of Ammonium Nitrate are as follows:
N2(g)+3H2(g)2NH3(g)
2NH3(g)+3O2(g)2HNO3(g)+2H2(g)
Stream 1 contains 61.24mol% of hydrogen; 22.38mol% of nitrogen and 16.38mol% of inert gases
(argon). Reaction 1 occurs in reactor 1 and forms 288molmin of ammonia and thus contains 15% of
nitrogen. The reactor effluents pass to condenser 1 which removes all of the ammonia to stream 3 and
none of the reactants and inert gases. To avoid build-up of the inert in the system, a purge stream is
withdrew from the recycle (stream 11). Reactor 2 is fed with 50molmin of oxygen in stream 9 and
ammonia. Reactions 2 and 3 occur in reactor 2. The reactor effluents pass through the condenser that
removes all the Ammonium Nitrate while everything else is recycled in stream 7.
The following information is given about the process:
The feed to the reactor contains 22.76mol% of nitrogen.
The total molar flow rate of stream 10 is 300molmin and consists of 70mol% of hydrogen;
25mol% of nitrogen and 5mol% of inert gases.
Calculate the total flow rates and compositions of streams 1;2;3;4;10;11 and 12. Also find the
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