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Rate of Leaching. In studying the rate of leaching of a substance A from solid particles by a solvent B, we may postulate that the
Rate of Leaching. In studying the rate of leaching of a substance A from solid particles by a solvent B, we may postulate that the rate-controlling step is the diffusion of A from the particle surface through stagnant liquid film of thickness out into the main stream (illustrated in Fig. 18B.8). The molar solubility of A in B is CA0, and the concentration in the main stream is CA. Fig. 18B. S Laching of A by dittusion into a atagnant iquid flm of E. (a) Obtain a differential equation for cA as a function of z by making a mass balance on A over a thin slab of thickness z. Assume that DAB is constant and that A is only slightly soluble in B. Neglect the curvature of the particle. (b) Show that, in the absence of chemical reactions in the liquid phase, the concentration profile is linear. (c) Show that the rate of leaching is given by NAz=DAB(cA0CA)
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