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Se colocan en un recipiente de vidrio, de 1L, 0.02mol de PCl 5(g) y se llevan a una temperatura de 200C, con lo cual el
Se colocan en un recipiente de vidrio, de 1L, 0.02mol de PCl
5(g)
y se llevan a una
temperatura de 200C, con lo cual el PCl
5(g)
se descompone de acuerdo con la
ecuacin:
)
(
2
)
(
3
)
(
5
g
g
g
Cl
PCl
PCl
Al medir las concentraciones de equilibrio, se encontraron los siguientes valores:
[PCl
5
] = 0.01076 mol/L
[PCl
3
] = 0.00924 mol/L
[Cl
2
] = 0.00924 mol/L
Con esta informacin, calcula la constante de equilibrio (K
e
):
5
2
3
PCl
Cl
PCl
K
e
3
10
93
.
7
01076
.
0
00924
.
0
00924
.
0
x
K
e
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