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Se colocan en un recipiente de vidrio, de 1L, 0.02mol de PCl 5(g) y se llevan a una temperatura de 200C, con lo cual el

Se colocan en un recipiente de vidrio, de 1L, 0.02mol de PCl

5(g)

y se llevan a una

temperatura de 200C, con lo cual el PCl

5(g)

se descompone de acuerdo con la

ecuacin:

)

(

2

)

(

3

)

(

5

g

g

g

Cl

PCl

PCl

Al medir las concentraciones de equilibrio, se encontraron los siguientes valores:

[PCl

5

] = 0.01076 mol/L

[PCl

3

] = 0.00924 mol/L

[Cl

2

] = 0.00924 mol/L

Con esta informacin, calcula la constante de equilibrio (K

e

):

5

2

3

PCl

Cl

PCl

K

e

3

10

93

.

7

01076

.

0

00924

.

0

00924

.

0

x

K

e

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