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Silver and Gold form a continuous series of solid solutions, and interdiffusion occurs by a vacancy mechanism. A diffusion couple was made by depositing a

Silver and Gold form a continuous series of solid solutions, and interdiffusion occurs by a vacancy mechanism. A diffusion couple was made by depositing a thick layer of Silver onto a gold substrate. At 1000 K the interdiffusion coefficient of silver into gold is 10-10 cm2/s and the interdiffusion coefficient of gold into silver is 2 x 10-11 cm2/s.
a) Whycanthetwodiffusioncoefficientsbedifferent?
b) Will the plane where the concentration if 50:50(metallurgical interface) move
during diffusion? If so, which way.
c) Will there be a net flux of vacancies through the inter during diffusion?On
which side of the interface would you expect to find voids (pores)?
d) Sketch the concentration profile at the junction after annealing at for 3 days at
1000K

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