Question
Suppose a battery was made using calcium (Ca) and bismuth (Bi) as the electrodes and had an operation temperature of 600 o C. Use the
Suppose a battery was made using calcium (Ca) and bismuth (Bi) as the electrodes and had an operation temperature of 600 oC. Use the Ca-Bi phase diagram and standard reduction potentials for Bi3+/Bi and Ca2+/Ca to answer the following questions.
Bi3+ + 3e- Bi; V0 = 0.308 V vs. NHE
Ca2+ + 2e- Ca; V0 = -2.87 V vs. NHE
(a) Calculate the theoretical open circuit voltage for this battery at standard conditions. Then, draw the voltage profile for the discharge until the composition of the cathode reaches a mole fraction of xCa = 0.625.
(b) Suppose you took a snapshot of the battery after it has discharged until the composition of the cathode is xCa = 0.55. Label the different components of the battery at this point in the schematic in the electrochemical cell below.
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