Question
Suppose we redefine the standard state as P=5 bar. Find the new standard fG values of the following substances. Part A: HCl(g) Part B: N2O(g)
Suppose we redefine the standard state as P=5 bar. Find the new standard fG values of the following substances. Part A: HCl(g) Part B: N2O(g) Part C: H(g)
My Answers: Part A: -95.3 kJmol1 Part B: 101.7 and for Part C: 205.3
I need help with parts D-F please.
Part D: Explain the results in terms of the relative entropies of reactants and products of the reaction in part A.
- Since the number of moles of reactants and products are the same, the decrease in volume affects the entropy of both equally, so there is no change in fG
-The entropy of the reactants is decreased more than the entropy of the product. Since the product is relatively more favored, there is no change in fG
-The entropy of the product is decreased more than the entropy of the reactant. Since the product is relatively less favored, there is no change in fG
Part E: Explain the results in terms of the relative entropies of reactants and products of the reaction in part B.
- Since the number of moles of reactants and products are the same, the decrease in volume affects the entropy of both equally, so fG is less positive.
-The entropy of the reactants is decreased more than the entropy of the product. Since the product is relatively more favored, fGis less positive.
-The entropy of the product is decreased more than the entropy of the reactant. Since the product is relatively less favored, fG is less positive.
Part F: Explain the results in terms of the relative entropies of reactants and products of the reaction in part C.
- Since the number of moles of reactants and products are the same, the decrease in volume affects the entropy of both equally, so fG is more positive. |
- The entropy of the reactants is decreased more than the entropy of the product. Since the product is relatively more favored, fG is more positive. |
- The entropy of the product is decreased more than the entropy of the reactant. Since the product is relatively less favored, fG is more positive. |
Step by Step Solution
There are 3 Steps involved in it
Step: 1
Get Instant Access to Expert-Tailored Solutions
See step-by-step solutions with expert insights and AI powered tools for academic success
Step: 2
Step: 3
Ace Your Homework with AI
Get the answers you need in no time with our AI-driven, step-by-step assistance
Get Started