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The atmospheric CO 2 concentration is 398 ppm. Assume that the air is in equilibrium with a water body that has a pH of 5.8.

The atmospheric CO2 concentration is 398 ppm. Assume that the air is in equilibrium with a water body that has a pH of 5.8. Estimate the concentrations of dissolved total CO2 (CO2(aq) +H2CO3), bicarbonate (HCO3-) and carbonate (CO32-). Henrys law constant for carbon dioxide/water is kH = 29.41 atm mol-1. The equilibrium constants for dissociation of carbonic acid to bicarbonate, and of bicarbonate to carbonate is H2C03 = 10-6.35 and HCO3 =10-10.38 respectively.

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