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The cyclic Voltammogram of the first in a series of pyridylamine complexes is shown below. HO TPA EMPA [Fe(BMPA-Pry]CI 2.1- Current (A) S FEM(MV) VS
The cyclic Voltammogram of the first in a series of pyridylamine complexes is shown below. HO TPA EMPA [Fe(BMPA-Pry]CI 2.1"- Current (A) S FEM(MV) VS SHE SOLVENT :MECN 203 200 242 860 Fe(BMPA)(CI) Fe(BMPA)(C104) Fe(BMPA)(OT) Fe(TPA)(MeCN) (CIO4)2 E12 - 4 mV vs. Ag/Agci - 203 mV vs. SHE 0.3 0.1 0.0 -0.1 Potential (V) vs. Ag/Agci BERTO, HOFFMAN, MURATA, LANDENBERGER, ALP, ZHAO & LEHNERT, J. AM. CHEM. SOC. 2011, 133, 16714 Is the reduction shown in the voltammogram chemically reversible? a. Based on the data in the table, which of the BMPA complexes is easiest to oxidize? b. Can you make an argument based on the counterion to explain this trend in the reduction potentials of the BMPA complexes
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