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The elementary gas - phase reaction ( C H 3 ) 3 C O O C ( C H 3 ) 3 C 2 H

The elementary gas-phase reaction
(CH3)3COOC(CH3)3C2H6+2CH3COCH3
AB+2C
is carried out isothermally at 400K in a flow reactor with no pressure drop. The reaction rate constant
at 50C is 10-4min-1 and the activation energy is 85kJmol. Pure di-tert-butyl peroxide enters the
reactor at 10atm and 127C and a molar flow rate of 2.5molmin.
a. Using a conversion-based approach, calculate analytically the plug-flow volume and space time
for a CSTR achieving 90% conversion.
b. Using a conversion-based approach, obtain x,FA,FB, and FC numerically (python) as a function
of PFR volume. Plot (i.)x and (ii.)FA,FB, and FC as a function of reactor volume. Estimate the
space time necessary to achieve 90% conversion.
c. Using a molar flowrate-based approach, obtain x,FA,FB, and FC numerically (python) as a
function of PFR volume. Plot (i.)x and (ii.)FA,FB, and FC as a function of reactor volume.
Estimate the space time necessary to achieve 90% conversion. (The answer should be identical to
part b.)
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