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The figure below shows both the emission and fluorescence spectrum of anthracene in a suitable solvent. (i) Indicate the approximate wavelengths the 00,01 and 02

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The figure below shows both the emission and fluorescence spectrum of anthracene in a suitable solvent. (i) Indicate the approximate wavelengths the 00,01 and 02 transitions in both spectra. [2 marks] (ii) Calculate the energy absorbed and emitted for the 0-2 transitions in both spectra. h=6.6261.014Js [6 marks] (iii) Both the absorption and emission spectra look similar. What is the name of this property of fluorescence. [2 marks] (iv) State, and explain with the aid of a diagram, the Frank Condon principle. [15 marks] (v) Why do the 0-0 transitions in the absorption and fluorescence not overlap? Explain with the aid of diagram. [15 marks]

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