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The following reaction takes place at 80.1C: Ru(NH 3 ) 5 Cl 2+ ( aq ) + H 2 O ( l ) Ru(NH 3

The following reaction takes place at 80.1C: Ru(NH3)5Cl2+ (aq) + H2O (l) Ru(NH3)5(H2O)3+ (aq) + Cl- (aq) The following time and concentration data are collected:

t (s) [Ru(NH3)5Cl2+] ln (Ru(NH3)5Cl2+) 1/(Ru(NH3)5Cl2+)
0 1.50 10-2 -4.20 66.7
1.00 10-3 1.08 10-2 -4.53 92.6
2.00. 10-3 7.78 10-3 -4.86 128.5
3.00. 10-3 5.61 10-3 -5.18 178.2
5.40. 10-3 2.55 10-3 -5.97 392
1.01. 10-2 5.46 10-4 -7.51 1830
4.00. 10-2 3.01 10-8 -17.3 3.32 107

Which of the following is the correct value of the rate constant?

3.28 1/Ms

4.19 1/s

419 1/s

328 1/Ms

328 1/s

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