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The lattice parameter for the cerium MOF Ce-UiO-66-BDC, which is structurally identical to UiO-66 but with Ce(IV) oxide nodes instead of r(IV) oxide nodes, is
The lattice parameter for the cerium MOF Ce-UiO-66-BDC, which is structurally identical to UiO-66 but with Ce(IV) oxide nodes instead of r(IV) oxide nodes, is a = 21.4727(3) A. How would the lattice parameter of the Ce(IV)-substituted MOF, Ce(IV)-UiO-66, change if 5% Ce(IV), 25% Ce(IV) and 55% Ce(V) were substituted for Zr(IV) in the framework? Plot the % Ce(TV) substitution versus the calculated lattice parameter.
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