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The lowest-lying excited states of the following complexes are metal-to-metal charge-transfer (MMCT) in character. Complex (1): [(H3N)5OsIINCOs(CN)5] Complex (2): [(NC)5Co111NCOs11(CN)5] (i) Identify clearly the nature
The lowest-lying excited states of the following complexes are metal-to-metal charge-transfer (MMCT) in character. Complex (1): [(H3N)5OsIINCOs(CN)5] Complex (2): [(NC)5Co111NCOs11(CN)5] (i) Identify clearly the nature of the HOMO and LUMO of each complex. (ii) One of the complexes undergoes photolysis in aqueous solution. State which complex and give reasons. (4 marks)
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