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The molecule propadiene adopts a staggered D2d structure. H-atoms 1 and 2 are in the xz-plane, H-atoms 3 and 4 in the yz-plane: The character
The molecule propadiene adopts a staggered D2d structure. H-atoms 1 and 2 are in the xz-plane, H-atoms 3 and 4 in the yz-plane: The character table of D2d indicates that z is an irreducible basis of the B2 representation and the pair {x,y} is an irreducible basis of the E-representation. Use the latter to construct a set of irreducible representation matrices for E
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