The monthly concentration of $C{O}_2$ is measured at Mauna Loa Observatory, Hawaii. Please estimate the $pH$ of rain given the newly measured value of $[C{O}_2]=426ppm.$ Consider the effect of $C{O}_2$ only. For ionization of carbonic acid: $K_{a1}={10}^{-6\mathrm{.}35}$ and $K_{a2}={10}^{-10\mathrm{.}33}*K_H={10}^{-1\mathrm{.}47}\frac{M}{a}tm$ for the dissolution of $C{O}_2.$ If assumptions are available, please make assumptions and simplify the equations to solve it