Answered step by step
Verified Expert Solution
Question
1 Approved Answer
The proton affinity, PA, of ammonia is defined as the change in energy for the reaction: NH4+(g)NH3(g)+H+(g) PA at 0K can be computed from other
The proton affinity, PA, of ammonia is defined as the change in energy for the reaction: NH4+(g)NH3(g)+H+(g) PA at 0K can be computed from other thermal data through consideration of the Born-Haber cycle (all substances except NH4Cl being gases): in which Elattice represents the lattice energy per mole of crystalline NH4Cl,153kcal/mole. IPH, the ionization energy of a mole of hydrogen atoms is 312kcal/mole, and the electron affinity of chlorine, EAcl, is 92.5kcal/mole. Using 75.1kcal/mole as the heat of formation of solid ammonium chloride, and 10.9kcal/mole as that of NH3(g), and looking up any other energies you may need (aside from the PA of ammonia), calculate PA of NH3. You may neglect contributions from PV work
Step by Step Solution
There are 3 Steps involved in it
Step: 1
Get Instant Access to Expert-Tailored Solutions
See step-by-step solutions with expert insights and AI powered tools for academic success
Step: 2
Step: 3
Ace Your Homework with AI
Get the answers you need in no time with our AI-driven, step-by-step assistance
Get Started