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The reactions of ,-unsaturated ketones such as I(R1 and R2 are both alkyl groups) with amines such as II (R3= alkyl) can give two different
The reactions of ,-unsaturated ketones such as I(R1 and R2 are both alkyl groups) with amines such as II (R3= alkyl) can give two different major organic products (i.e. excluding H2O as a product) depending on the reactions conditions employed. If some method of water removal is employed during the reaction (e.g. by using molecular sieves), product III is formed as the major product (Reaction A shown below) through a process involving several intermediates. If no means of removing water is employed, product IV is formed as the major product (Reaction B shown below) through a process involving one intermediate. What does the fact that H2O must be removed in Reaction A indicate about the reaction of I+II to form product III? Suggest structures for product III and product IV, and explain your rationale in picking these structures. Explain why product IV is formed in preference to product III in Reaction B (i.e. if H2O is not removed from the reaction mixture). The reactions of ,-unsaturated ketones such as I(R1 and R2 are both alkyl groups) with amines such as II (R3= alkyl) can give two different major organic products (i.e. excluding H2O as a product) depending on the reactions conditions employed. If some method of water removal is employed during the reaction (e.g. by using molecular sieves), product III is formed as the major product (Reaction A shown below) through a process involving several intermediates. If no means of removing water is employed, product IV is formed as the major product (Reaction B shown below) through a process involving one intermediate. What does the fact that H2O must be removed in Reaction A indicate about the reaction of I+II to form product III? Suggest structures for product III and product IV, and explain your rationale in picking these structures. Explain why product IV is formed in preference to product III in Reaction B (i.e. if H2O is not removed from the reaction mixture)
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