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The second order decomposition reaction 2 A ( g ) B ( g ) + C ( g ) is carried out in a 2

The second order decomposition reaction
2A(g)B(g)+C(g)
is carried out in a 20cm ID tubular reactor packed with catalyst pellets of 1cm diameter. The reaction is internal-diffusion limited. Pure A enters the reactor at a superficial velocity of 1ms-1, a temperature of 250C, and a pressure of 500kPa. Experiments carried out on smaller pellets where the surface reaction is limiting yielded a reaction rate constant of 0.5m6mol-1men-2s-1(see the additional information at the end of the question)
i. Assuming the reactor is isothermal and pressure drop is negligible, derive an equation to calculate the length (L) of this packed bed reactor (PBR) required to achieve a conversion (X).
ii. Calculate the length of bed necessary to achieve 95% conversion.
iii. Calculate the pressure drop in the bed, if the reactor is isothermal. If you are not sure about your answer in part ii, assume L=1m.
iv. Discuss how a large pressure drop affects the length of bed necessary to achieve 95% conversion and whether the assumption of constant pressure is reasonable for a gas flowing through a PBR.
Additional Data:
Effective diffusivity: 110-10m2s-1
Bed Porosity: 0.5
Density of A at inlet conditions:
A=0.7kgm-3
Gas constant R=8.314m2PaK-1mol-1
Bulk density of bed: 8102gm-3 Internal surface area: 400mcat2g-1 Viscosity of A at inlet conditions:
HA=1.310-5kgm-1s-1
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