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The SO 3 used in the manufacture of sulfuric acid is obtained by the oxidation of SO 2 in the presence of an appropriate catalyst:

The SO3 used in the manufacture of sulfuric acid is obtained by the oxidation of SO2 in the presence of an appropriate catalyst:
SO2+0.5O2 SO3
If one starts with a feed of the composition shown below, determine the temperature at which the fluid must leave the reactor if the equilibrium effluent composition corresponds to 95% conversion of the SO2 fed to the reactor.
O2------>13 mol% feed composition
N2------>79 mol% feed composition
SO2----->8 mol% feed composition
The effluent pressure is 2 atm. At 600C the standard Gibbs free-energy change for standard states of unit fugacity is known to be 3995 cal/mol for the reaction as written above. For the temperature range of interest, the standard heat of reaction may be taken as a constant equal to 22,650 cal/mol.

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