Question
The temperature dependence of the first-order rate constant is: T(K) . . . . k(s -1 ) 800 ....0.00027 825 ....0.00049 850 ....0.00086 875 ....0.00143
The temperature dependence of the first-order rate constant is: T(K) . . . . k(s-1)
800 ....0.00027 825 ....0.00049 850 ....0.00086 875 ....0.00143 900 ....0.00234 925 ....0.00372
1.) Calculate the activation energy, in kJ/mol. Use all data points and do a linear regression using calculator or Excel. Do not pick 2 data points. This is less accurate and assumes all data points are equally good.
2.) Calculate the frequency factor A (in s -1).
3.)
The activation energy for the isomerization of cyclopropane to propene is 274 kJ/mol. By what factor does the rate of this reaction increase as the temperature rises from 257 to 292 oC? (The factor is the ratio of the rates.)
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