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Thermodynamics: Calculate (can be done in a spreadsheet) the equilibrium constant for quartz from 5-100 degrees C at five-degree increments using the Van't Hoff equation
Thermodynamics:
Calculate (can be done in a spreadsheet) the equilibrium constant for quartz from 5-100 degrees C at five-degree increments using the Van't Hoff equation
Find the blanks of gibbs free energy, log K, PK, and Hr of quartz
Then plot the results Log10 (KT) (ordinate) vs temperature (abscissa)
What do these results mean?
AG" log KPK , . Component AG: (Drever, App II) kJ/mol H4S104 -1307.9 quartz -856.3 water -237.14 -1457.3 -910.7 -285.83 van't Hoff, quartz, 5-100C LogK, -log K. + AH,/R/In(10) * (1/T, - 1/T.) quartz, 25 -3.00 -3.50 Quartz log K dH t, C log Kit (qtz) 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 logk (quartz) -4.00 -4.50 0 50 100 150 Temperature, C AG" log KPK , . Component AG: (Drever, App II) kJ/mol H4S104 -1307.9 quartz -856.3 water -237.14 -1457.3 -910.7 -285.83 van't Hoff, quartz, 5-100C LogK, -log K. + AH,/R/In(10) * (1/T, - 1/T.) quartz, 25 -3.00 -3.50 Quartz log K dH t, C log Kit (qtz) 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 logk (quartz) -4.00 -4.50 0 50 100 150 Temperature, CStep by Step Solution
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