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What is the mechanism of this reaction? Table 1. Reaction parameters studiesa NH2 + - acid (x, equiv.) oxidant (0.2M) 100 , 1h 2 NH2

image text in transcribedWhat is the mechanism of this reaction?

Table 1. Reaction parameters studiesa NH2 + - acid (x, equiv.) oxidant (0.2M) 100 , 1h 2 "NH2 1 entry acid (x, equiv.) oxidant yield (%) 1 TBHP 35 2 HCI (10) TBHP 61 3 CH3COOH (10) TBHP 68 4 (10) TBHP 61 5 ,0 (1,0) TBHE 80 6 (10) TBHP 83 7 BF3.Et0 (10) TBHP 62 8 (10) , 74 9 (10) 58 10 f (10) CHP 79 11 (10) K2S,08 64 12 (10) Oxone 47 139 (10) TBHP 86 145 f (10) TBHP 87 154 (0.5) TBHP 89

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