What quantity in moles of $C{H}_{3}N{H}_{3}Cl$ need to be added to $200\mathrm{.}0mL$ of a $0\mathrm{.}500M$ solution of $C{H}_{3}N{H}_2($ Kb for $C{H}_{3}N{H}_2$ is $4\mathrm{.}4{10}^{-4})$ to make a buffer with a $pH$ of $11\mathrm{.}05?$