Which acid and its conjugate base would be the best buffer at pH =4.7?

Which acid and its conjugate base would be the best buffer at pH=4.7 ? formic acid; Ka=1.8104 2-amino-2-hydroxymethyl-propane-1,3-diol (Tris); Ka=6.3109 4-morpholineethanesulfonic acid (MES); Ka=7.9107 acetic acid; Ka=1.8105 4-(2-hydroxyethyl)piperazine-1-ethanesulfonic acid (HEPES); Ka=3.2108