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Why ionization by electron impact is more effective than ionization in collisions of heavy particles? Why vibrational excitation of molecules by electron impact mostly proceeds

Why ionization by electron impact is more effective than ionization in collisions of heavy particles?

Why vibrational excitation of molecules by electron impact mostly proceeds through intermediate electron attachment and not by simple elastic collision?

How to explain that vibrationally excited molecule is able to withstand up a billion of collisions without losing its excitation?

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