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You and your lab partner are studying the rate of a reaction, A + B --> C. You make measurements of the initial rate under

You and your lab partner are studying the rate of a reaction, A + B --> C. You make measurements of the initial rate under the following conditions:

Experiment [A] (M) [B] (M) Rate (M/s)
1 0.8 0.7
2 1.6 0.7

(a) Which of the following reactant concentrations could you use for experiment 3 in order to determine the rate law, assuming that the rate law is of the form, Rate = k [A]x [B]y? Choose all correct possibilities.

[A] = 0.8 and [B] = 1.4[A] = 1.6 and [B] = 1.4[A] = 1.6 and [B] = 0.7[A] = 2.4 and [B] = 0.7[A] = 4.0 and [B] = 0.7[A] = 0.8 and [B] = 2.1[A] = 1.6 and [B] = 2.1[A] = 3.2 and [B] = 0.7

(b) For a reaction of the form, A + B + C --> Products, the following observations are made: doubling the concentration of A increases the rate by a factor of 4, doubling the concentration of B has no effect on the rate, and doubling the concentration of C increases the rate by a factor of 4. Select the correct rate law for this reaction from the choices below.

Rate = k[A][B][C]

Rate = k[A][C]

Rate = k[A]2 [C]

Rate = k[A][C]2

Rate = k[A]2 [C]2

Rate = k[A]3 [C]

Rate = k[A][C]3

(c) By what factor will the rate of the reaction described in part (b) above change if the concentrations of A, B, and C are all halved (reduced by a factor of 2)? The rate will be the original rate multiplied by a factor of .

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