You need to prepare $100\mathrm{.}0$ mL of a pH $4\mathrm{.}00$ buffer solution using $0\mathrm{.}100$ M benzoic acid $($p Ka $=4\mathrm{.}20)$ and $0\mathrm{.}200$ M

sodium benzoate.

How many milliliters of each solution should be mixed to prepare this buffer?