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You oversee a polymer synthesis laboratory which only has the chemicals labelled A through R below. a . Which combination of molecules could be used
You oversee a polymer synthesis laboratory which only has the chemicals labelled
through below.
a Which combination of molecules could be used in stepgrowth polymerizations?
Draw reactions and their products.
b What molecules could be used if a crosslinked material is desired? Draw the
reaction and product.
A sample of polyamideNylon produced by "ideal" stepgrowth polymerization
of the monomer is found to contain mol of end groups by nuclear
magnetic resonance NMR
a Calculate the numberaverage molecular weight of this sample of Nylon
b Calculate the extent of reaction of the stepgrowth polymerization.
c Assuming "ideal" stepgrowth polymerization statistics, calculate the weight
average molecular weight.
d Estimate the weight fraction of chains in this sample that have a molecular weight
less than HINT: integration may be necessary
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