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You want to polymerize a solution of 100g/L of acrylamide in methanol with 0.1M isobutyl peroxide. For acrylamide, kp2/kt=22L/mol at 25C. Termination takes place only
You want to polymerize a solution of 100g/L of acrylamide in methanol with 0.1M isobutyl peroxide. For acrylamide, kp2/kt=22L/mol at 25C. Termination takes place only be combination. At this temperature, the half-life of isobutyl peroxide is 9.0h and its efficiency in methanol is f=0.3. a) What is the initial steady-state rate of polymerization? b) How much polymer can you make in the first 10 minutes of polymerization in 1L of solution
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