Use the ClausiusMossotti expression in Equation (8.13) and Table 8.2 to estimate permittivities of SnO 2 (rutile-type,
Question:
Use the Clausius–Mossotti expression in Equation (8.13) and Table 8.2 to estimate permittivities of SnO2 (rutile-type, P42/mnm, Z = 2, a = 4.74 Å, c = 3.19 Å), TiO2 (rutile-type, a = 4.59 Å, c = 2.96 Å) and ZrO2 (baddeleyite-type, P21/c, Z = 4, unit-cell volume = 141 Å). Does the Clausius–Mossotti equation give a reasonably accurate estimate for each compound when compared to the experimental values of εr given in Table 8.1? If not, what is the origin of the discrepancy?
Equation (8.13)
Table 8.2
Table 8.1
Transcribed Image Text:
a= V 4 2 Er (+2) [CGSes : a in , V, in A]
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Calculated values are r 13 SnO 2 r 20 ZrO 2 and r 43 TiO 2 Th...View the full answer
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Related Book For
Solid State Materials Chemistry
ISBN: 9780521873253
1st Edition
Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt
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