We can approximate the Sn 2+ coordination in the hypothetical CsCl-type SnO of the previous problem by
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We can approximate the Sn2+ coordination in the hypothetical CsCl-type SnO of the
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previous problem by an SnHs cube. The point-group symmetry for a cube is m3m (On). In SnHg, the Sn 5s and 5p orbitals have ang and 1 symmetry, respectively. The hydride ligands form two triply degenerate SALCs with thu and t2g symmetry, as well as two singly degenerate SALCs with aig and a2u symmetry. Use this information to construct an approximate MO diagram for a cubic SnHg6 molecule. What is the degeneracy, bonding character, and symmetry of the HOMO and LUMO?
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The MO diagram for a SnH 8 6 ion is shown below The singly d...View the full answer
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Related Book For
Solid State Materials Chemistry
ISBN: 9780521873253
1st Edition
Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt
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