Example 5.6: Maximum of entropy The entropy S (here SMB) and the canonical partition function Z are
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Example 5.6: Maximum of entropy The entropy S (here SMB) and the canonical partition function Z are related as e.g. in Eq. (5.19)
which can be rewritten in the form (with gi = 1)
S = k(lnZ + E/kT), Z=
i e−i/kT, Pi =
1 Z
e−i/kT . (5.61)
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