Question: In a chemical reaction run at a certain temperature, the concentration C of a certain reactant at time t is given by 1/C = kt+1/C
In a chemical reaction run at a certain temperature, the concentration C of a certain reactant at time t is given by 1/C = kt+1/C0, where C0 is the initial concentration and k is the rate constant. Assume the initial concentration is known to be 0.04 mol/L exactly. Assume that time is measured with negligible uncertainty.
a. After 30 s, the concentration C is measured to be 0.0038 ± 2.0 × 10−4 mol/L. Estimate the rate constant k, and find the relative uncertainty in the estimate.
b. After 50 s, the concentration C is measured to be 0.0024 ± 2.0×10−4 mol/L. Estimate the rate constant k and find the relative uncertainty in the estimate.
c. Denote the estimates of the rate constant k in parts (a) and (b) by k̂1 and k̂2, respectively. The geometric mean √k1k2 is used as an estimate of k. Find the relative uncertainty in this estimate
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a C 0 004 t 30 C 00038 C 00002 k 1t1C 1C 0 130C 56 794 ln k ... View full answer
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