Dimethyl azodicarboxylate (see margin) takes part in the Diels-Alder reaction as a dienophile. Write the structure of

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Dimethyl azodicarboxylate (see margin) takes part in the Diels-Alder reaction as a dienophile. Write the structure of the product of cycloaddition of this molecule with each of the following dienes. 

(a) 1,3-Butadiene; 

(b) trans,trans-2,4-hexadiene; 

(c) 5,5-dimethoxycyclopentadiene; 

(d) 1,2-dimethylenecyclohexane. Ignore the stereochemistry at nitrogen in the products (amines undergo rapid inversion)

CH,OČ N=N COCH3 Dimethyl azodicarboxylate

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Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

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